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The first structures of strontium xanthates Sr(S 2 COR) 2 (ROH) 3  ·  x ROH [ x =0, R=Et ( 1 ),  i Pr ( 2 );  x =1, R= t Bu ( 3 )] have been determined. All three species adopt an approximately pentagonal bipyramidal SrS 4 O 3  coordination sphere about the metal, although the lattice structures differ across the series and are determined by the hydrogen bonding network afforded via the alcohol moieties.

The structures of strontium xanthates Sr(S 2 COR) 2 · x ROH (R=Et, Pr i , Bu t )