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Conditions describing the behaviour of the kink of isobars at the dew line in t;-x-phase diagrams of binary mixtures are proved using the second law. These conditions are interesting in connection to the compatibility of Serogodsky's and van Platen's cycles with the second law of thermodynamics.

Second Law Induced Existence Conditions for Isothermal 2-Phase Region Cyclic Processes in Binary Mixtures