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In this paper an estimate for the reversible molar heat supply needed for fully separating a certain mixture is given on the basis of thermodynamic balance equations. It is shown that in order to estimate this heat supply one should solve the problem of selecting the optimal separation sequence. The algorithm solving this task is given. This algorithm allows to select the separation sequence on the basis of preliminary calculations, knowing only the properties of the component that one wants to separate. The solution algorithm is demonstrated for an exemplary system: a gas-fractionation plant.

The Rule of Temperature Coefficients for Selection of Optimal Separation Sequence for Multicomponent Mixtures in Thermal Systems