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Initial concentration dependence of dimethyl sulfoxide (DMSO) oxidation has been investigated by pulsed discharge plasma in air with water droplets spray for the first time. Dimethyl sulfone (DMSO 2 ) was produced by the oxidation of DMSO, and the concentration of DMSO 2  linearly increased with an increase in the treatment time. The conversion rate of DMSO in the initial concentration of 443 mg/L was 51% after 10-h treatment. The experimental yield of DMSO 2  was approximately 70% of the theoretical yield of DMSO 2 . These results indicated that mineralization of DMSO is possible by further treatment and that other oxidized intermediate compounds besides DMSO 2  were produced by the oxidation of DMSO. The kinetics and efficiency of DMSO conversion to DMSO 2  were investigated under different initial concentrations of DMSO. The DMSO conversion rate and efficiency increased with the rise in the initial DMSO concentrations. It was found that DMSO was efficiently oxidized at a higher initial concentration of DMSO.

Initial Concentration Dependence of Dimethyl Sulfoxide Oxidation by Pulsed Discharge Plasma in Air with Water Droplets Spray