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The Advanced Oxidation Processes (AOPs) are powerful water treatment processes that utilize free radicals to destroy contaminants. The chemistry of these processes is sufficiently complicated that the correct route to process optimization is not always obvious. Examples of simple and complex applications of a competitionkinetic modeling method to the treatment of nitro compounds in water are described. The method used can provide a great deal of information that is useful in AOP optimization, while requiring a minimum amount of site data, making it an ideal tool for treatability assessments and rapid initial process optimization.

Kinetic Modeling for Process Optimization During the Free-Radical Treatment of Nitro Compounds in Aqueous Solution