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Amorphous Co 78 Si 8 B 14  alloy, as a new potential catalyst, has hardly been used in the degradation of organic pollutant activated by peroxymonosulfate (PMS). In the study, the degradation performance of Orange II aqueous solution by PMS activated by amorphous Co 78 Si 8 B 14  alloy in a heterogeneous catalytic process was studied at ambient temperature. The effects of initial solution  pH , amorphous Co 78 Si 8 B 14  alloy dosage and PMS concentration on Orange II degradation were examined in batch experiments. The results show that decolorization was strongly influenced by initial solution  pH , amorphous Co 78 Si 8 B 14  alloy dosage, and PMS concentration. The decolorization rate increased with the increase in  pH  value from 3 to 6.45. In contrast, it decreased sharply when the  pH  value of the solution increased from 6.45 to 11. The decolorization rate increased as the amorphous Co 78 Si 8 B 14  alloy dosage and PMS concentration increased. Finally, the potential mechanism of Orange II removal by amorphous Co 78 Si 8 B 14  alloy/PMS system was proposed systematically by comparing with the Co 2+ /PMS system.

Peroxymonosulfate oxidation process activated with heterogeneous amorphous Co 78 Si 8 B 14 alloy for degradation of Orange II