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The microstructural evolution, solidification behavior, phase relationships, microhardness and room temperature magnetic properties of the hypoeutectic Fe 60 Al 40- n  Hf  n   ( n  = 1, 3, and 5 at.%) compositions are investigated in detail. The micro-structure of the studied alloys is composed of Fe–Al based dendrites and eutectic mixture. The components of the eutectic are B2 Fe–Al based and HfFe 6 Al 6  τ 1  phases. With increasing Hf fraction, the amounts of eutectic and τ 1  phases increase continuously which results in significant strengthening. Based on the differential scanning calorimetry results, the eutectic reaction temperature is measured as 1251 °C. Fe 60 Al 40- n  Hf  n   alloys show weak room temperature ferromagnetism and their magnetization values also increase with increasing Hf content.

Microstructure, phase relationships and microhardness of Fe 60 Al 40– n Hf n alloys ( n = 1, 3, and 5 at.%)