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The partial and integral enthalpies of mixing of Al–Fe–Ge melts have been measured by high-temperature calorimetry at 1740 ± 5 K. The integral enthalpies of mixing at 1173 K, are about 4 to 6 kJ mol –1  less negative than determined by electromotive force measurement [ 9 ]. The integral enthalpies of mixing have been also estimated on the basis of the Bonnier geometric model. The calculated values show a reasonable agreement with experimental data for  x  Ge  &gt; 0.3. A difference between experimental and estimated integral enthalpies of mixing (up to 2.5 kJ mol –1 ) is observed for ternary alloys with low germanium content.

Enthalpies of mixing of liquid Al–Fe–Ge alloys