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Displacement reactions have been studied in the Fe-Ni-B system at 925°C and in the Fe-Co-B system at 900°C, together with the phase relations existing in these systems at the same temperatures. Although the isothermal crosssections show a clear resemblance, the morphology ofthe reaction layers in the Ni/Fe2B and Co/Fe2B diffusion couples was different. It is shown that the reaction layer morphology is in line with thermodynamic deductions from the slopes of the conodes in the phase diagrams.

Reactions and Phase Relations in the Systems Fe-Ni-B and Fe-Co-B / Reaktionen und Phasenbeziehungen in den Systemen Fe-Ni-B und Fe-Co-B