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The oxidation behavior of Super 304 H, Sanicro 25, HR3C and HR6W steels, which are recommended for use in ultra-supercritical power plants, as well as corrosion resistant X2CrNiMo17-12-2 steel was studied in this work. Oxidation tests were carried out under thermal shock conditions in an oxygen-rich environment (containing 50 vol. % water vapor) at a temperature equal to 750 °C. The investigated steels (excluding X2CrNiMo17-12-2 steel) are characterized by good oxidation resistance under thermal shock conditions. A highly protective Cr 2 O 3  layer was formed in the internal part of scales growing on the surfaces of investigated steels. The X2CrNiMo17-12-2 steel has worse oxidation resistant properties than the other grades of steels.

Oxidation Resistance of Austenitic Steels under Thermal Shock Conditions in an Environment Containing Water Vapor