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A trimeric β-O-4 lignin model bearing a styrene unit was polymerized in the presence of azobisisobutyronitrile as an initiator of free radical polymerization. The polymer analysis achieved by size exclusion chromatography (SEC),  1 H,  13 C,  31 P NMR, matrix-assisted laser desorption ionization combined with time-of-flight mass spectrometry (MALDI-ToF MS), differential scanning calorimetry, and thermogravimetry indicated its well-defined structure with good thermal stability at temperatures usually applied for alkaline pulping. SEC analysis proved a high degree of polymerization despite the size of the phenolic β-O-4 units in the polymer structure. MALDI-ToF spectrometry indicated that the polymer is composed of phenolic β-O-4 elements only. The chemical reactivity under alkaline conditions of the polymer was studied by both HPLC and  31 P NMR. These two methods revealed two main concurrent processes, which include an oxidation of the phenol part followed by C α -C β  bond cleavage, and a formation of a quinone methide followed by its β-O-4 bond cleavage.

holzforschung

Synthesis of a lignin polymer model consisting of only phenolic β-O-4 linkages and testing its reactivity under alkaline conditions 10 th  EWLP, Stockholm, Sweden, August 25–28, 2008