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Suberin from extractive-free cork from  Quercus suber  L. was depolymerised by methanolysis using different sodium methanolate (NaOMe) concentrations. 1% and 3% NaOMe completely removed suberin from cork (54%–56% of extractive-free cork), but for lower concentrations there was incomplete solubilisation; with 0.05% NaOMe, only approximately 80% of total suberin was removed. The monomeric composition of the extracts differed significantly: for the 0.05% NaOMe, only alkanoic acids and diacids were found; the yield of v-hydroxy acids increased with reactant concentration, as well as alkanols and ferulic acid.

holzforschung

Fragmentation of Suberin and Composition of Aliphatic Monomers Released by Methanolysis of Cork from Quercus suber L.,Analysed by GC-MS, SEC and MALDI-MS