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The distribution of ethyl acetate extracts and 4,8-dihydroxy-5-methoxy-2-naphthaldehyde (compound I), which is a major constituent of the extracts obtained from the blackened heartwood of  Diospyros kaki , was analyzed via gas chromatography-mass spectrometry (GC-MS) and time-of-flight secondary ion mass spectrometry (ToF-SIMS). According to GC-MS, the extracts and compound I are high in concentration at the pith and at the edges of the blackened heartwood. ToF-SIMS analysis revealed a peak at a mass-to-charge ratio of ( m/z ) 218, which is characteristic of the ionic form of compound I. The ToF-SIMS imaging of compound I in the blackened heartwood based on  m/z  218 shows that compound I is located in parenchyma cells and their neighboring axial elements.

holzforschung

Distribution of extracts including 4,8-dihydroxy-5-methoxy-2-naphthaldehyde in  Diospyros kaki  analyzed by gas chromatography-mass spectrometry and time-of-flight secondary ion mass spectrometry