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4-(3-(Trifluoromethyl)benzylthio)phthalonitrile ( 1 ) was synthesized. Metal-free phthalocyanine  2 , zinc(II) phthalocyanine  3  and cobalt(II) phthalocyanine  4  were synthesized starting with dinitrile compound  1 . Photodynamic therapy properties of  2  and  3  were studied.

heterocyclic communications

Synthesis of fluorine-containing phthalocyanines and investigation of the photophysical and photochemical properties of the metal-free and zinc phthalocyanines