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Methyl 2-[(cyanophenoxy)methyl]-3-furoates obtained from methyl 2-(chloromethyl)-3-furoate and salicylonitriles undergo tandem cyclization in the presence of excess  t -BuOK in N,N-dimethylformamide (DMF) solution at 65°C to give substituted benzofuro[3,2- b ]furo[2,3- d ]pyridin-4(5 H )-ones, derivatives of a novel heterocyclic system.

Synthesis of benzofuro[3,2- b ]furo[2,3- d ]pyridin-4(5 H )-ones, derivatives of a novel heterocyclic system