English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

The hydrolysis of phosphinic esters is an important transformation that may be performed under acidic or basic conditions on conventional heating. A series of cyclic phosphinates, 1-alkoxy-3-methyl or 3,4-dimethylphospholane oxides, has now been hydrolyzed under microwave (MW) conditions in the presence of 0.1 or 0.5 equivalents of  p -toluenesulfonic acid that served not only as the catalyst but also as a MW absorber. The later phenomenon was proved separately. The pseudo-first-order rate constants for the hydrolyses performed by the new approach were determined and a reactivity order was setup. The model reactions investigated were transplanted into flow MW accomplishment.

MW-assisted hydrolysis of phosphinates in the presence of PTSA as the catalyst, and as a MW absorber