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PP/nano-CaCO 3  composites with different interfacial interaction were prepared by addition of compatibilizers with the same polar groups but different backbones. The non-isothermal and isothermal crystallization behavior of PP/nano- CaCO 3  composites was investigated using differential scanning calorimetry (DSC). The results indicated that the interfacial interaction between PP and nano-CaCO 3  increased the crystallization temperature and crystallization rate of PP due to the heterogeneous nucleation of nano-CaCO 3 . The interfacial interaction between nano- CaCO 3  and compatibilizer further increased the crystallization temperature and crystallization rate of PP and induced the formation of β-crystal of PP due to the synergistic effect of heterogeneous nucleation between nano-CaCO 3  and compatibilizer. This synergistic effect of heterogeneous nucleation between nano- CaCO 3  and compatibilizer depended on the interfacial interaction between compatibilizer and PP matrix. The increased compatibility between compatibilizer and PP matrix favoured the heterogeneous nucleation between nano-CaCO 3  and compatibilizer

e-polymers

Role of interfacial interaction on the crystallization behavior and melting characteristics of PP/Nano-CaCO3 composites modified with different compatibilizers