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Part 2 of the study investigates morphologies of epoxy thermoset / thermoplastic blends obtained with formulations of the thermoset hardeners. The thermosetting matrices are composed of one epoxy resin crosslinked by a mixture of two aromatic diamine hardeners, namely MCDEA+DDS or MDEA+DDS (DDS is 4,4’-diaminodiphenylsulfone, MCDEA is 4,4’-methylenebis-(3-chloro-2,6- diethylaniline), MDEA is 4,4’-methylenebis-(2,6-diethylaniline). The blends are made at a fixed concentration of thermoplastic (poly(vinyl methyl ether), PVME, 10wt%) whereas three different cure temperatures are chosen and the matrix composition is varied by the ratio of DDS. DDS is a PVME-insoluble diamine whereas MDEA or MCDEA are PVME-soluble diamines.

e-polymers

Tuning morphologies of thermoset / thermoplastic blends Part 2: Phase separation of poly(vinyl methyl ether), PVME, using amine mixtures as thermoset hardeners