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A series of polystyrene- block -poly(1,2-butadiene)- block -poly(2-vinylpyridine) (SBV) triblock terpolymers were used to prepare blends with symmetric polystyrene- block -poly(2-vinylpyridine) (SV) and poly(2-vinylpyridine)- block -poly- (cyclohexyl methacrylate) (VC) diblock copolymers. Morphological characterization was carried out by transmission electron microscopy. These triblock terpolymers self-assemble into various core-shell type or lamellar morphologies. In the SBV/SV blends, macrophase separation between the two block copolymers, continuous centrosymmetric lamellae and stacks of non-centrosymmetric lamellae with antiparallel orientation were found. In the blends of SBV/VC, macrophase separation was never observed, what is due to the specific interactions between S and C domains. These systems showed among other morphologies also a cylindrical morphology in which rings surround the cylinders.

Novel pattern formation in blends of asymmetric ABC triblock terpolymers