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Optically active photochromic copolymers, deriving from methyl methacrylate (MMA) and the methacrylic ester of ( S )-3-hydroxypyrrolidine linked through the nitrogen atom to the highly conjugated photochromic 4'-(β-cyano-β- (methylsulfonyl)vinyl)-4-azobenzene moiety, have been prepared and characterized with the aim to evaluate the effect on their chiro-optical and thermal properties exerted by the insertion of inactive MMA groups along the main chain. The results indicate that these properties are still remarkable at a content of photochromic units as low as 26 mol-%.

e-polymers

Methacrylic polymers bearing side-chain permanent dipole azobenzene chromophores spaced from the main chain by chiral moieties: Part 2 1 : Copolymers with methyl methacrylate