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In this study, Ni–Y and Ce–Y zeolites are prepared using synthesized Na–Y zeolite through solid-state ion-exchange method. The adsorptive desulfurization of a model gasoline containing 194, 116 and 72 ppmw sulfur is evaluated in a batch system under ambient conditions. A dynamic model is established in order to investigate the performance of the adsorption process. The model predictions are compared with the obtained experimental results for thiophene adsorption on Ni–Y and Ce–Y zeolites from model solution containing different concentrations of thiophene, and a good agreement is observed. The model parameters: diffusivity and mass transfer coefficient are estimated by comparing the model predictions and experimental data.

A Mathematical Modeling and Experimental Study on Adsorptive Desulfurization of Model Gasoline Using Synthesized Ni–Y and Ce–Y Zeolites