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Two new Cu( ii )-based coordination polymers (CPs) with the chemical formulae of [CuL(bimmb) 0.5 ]n( 1 , bimmb is 4-bis(imidazole-1-ylmethyl)benzene) and [CuL(bbibp)]n( 2 , bbibp is 4,4'-bis(benzoimidazo-1-yl)biphenyl) have been successfully prepared by the reaction of 3,3'-azodibenzoic acid (H 2 L) ligand and metal salt Cu(NO 3 ) 2 ·3H 2 O in the presence of different nitrogen-donor coligands. In the bioactive evaluation experiments, the treatment activity of the prepared CPs against periodontitis was examined. Enzyme-linked immunosorbent assay detection was used to test interleukin-18 (IL-18) and IL-6 contents released into the gingival crevicular fluid after the treatment of above CPs, and the real-time reverse transcription polymerase chain reaction was subsequently performed to measure the relative expression level of  HmuY  gene in the  Porphyromonas gingivalis .

Two Cu( ii )-based coordination polymers: Crystal structures and treatment activity on periodontitis