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Reaction of the methyl ester of N-acetyl-beta-D-neuraminic acid methyl glycoside with N-acetylimidazole yielded the corresponding 9-O-acetyl- and 4,9-di-O-acetyl derivatives. The structures of these compounds were confirmed by mass spectrometry and both 1H and 13C NMR spectroscopy. The compounds served as model substances in a comparative study of the rate of periodate oxidation of unsubstituted and of 9-O-acetylated-N-acetyl-neuraminic acids. This reaction was strongly hampered by the presence of the 9-O-acetyl group. The low molar absorbancy coefficient of N-acetyl-9-O-acetylneuraminic acid in the periodic acid/thiobarbituric acid assay can be explained by this retardation.

hoppe-seyler's zeitschrift für physiologische chemie

Synthesis of 9-O-Acetyl- and 4,9-Di-O-Acetyl Derivatives of the Methyl Ester of N-Acetyl- β -D-Neuraminic Acid Methylglycoside. Their Use as Models in Periodate Oxidation Studies