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An expanded theory based on the hydrogen-bond configuration has been applied to compounds with the structure analogous to the surface in adsorbents, ketone and the systems of ketone/aromatic alcohol. The melting temperature depression of pure crystal and co-crystal of the systems were well reproduced by the theory. The analysis revealed the hydrogen-bond characteristics of the systems and predicted negative mixing heats.

An Analysis of Phase diagrams of Ketone/Aromatic alcohol by a Theory Based on Hydrogen-bond Configuration