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Synthesis and preparation of a square pyramidal Fe(III) complex with an N2S2-type ligand which can provide a strong σ donor sets of 4-. The strong ligand field makes the Lewis acidity of the metal center decrease. The Fe(III) complex showed a intermediate spin state and reduced to Fe(II) species at -0.77 V vs. NHE. The complex also easily reacted with NO molecule under Ar atmosphere to form a nitrosyl complex, which is confirmed with an appearance of N-O stretching mode at 1809 cm. The reaction exhibited a clear spectral change: An absorption band at 525 nm shifted to 660 nm, which is responsible for a color change from reddish-orange to pale green. Furthermore, the same color change was also observed in a solid state.

transactions of the materials research society of japan

Characterization of an Fe(III) complex with a symmetric N&lt;sub&gt;2&lt;/sub&gt;S&lt;sub&gt;2&lt;/sub&gt;-type coordination environment and the reactivity for NO