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Graduate School ofPure and Applied Science University ofTsukuba, Tenodai 1-1-1 Tsukuba, lbaraki 305-8571, Fax: +81-029-860-4715, e-mail: OWASHI.Keigo@nims.go.jp Biomaterials center, National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan Department of Materials Engineering Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan. Graduate School oflnformation Science and Technology, Hokkaido University *corresponding author

Photo-isomerization of a phenylboronic acid bearing an azo group to switch sugar recognition