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Features of pnictogen O...N bonds were considered from the point of view of analyzing various geometric orientations of the neighboring nitro groups NO2...NO2 observed in molecular crystals. The “idealized” orientation for a pnictogen bond, where the nucleophilic fragment of the atom O of one nitro group was directed to the electrophilic site of the atom N of the other one, and the “stacking” orientation, which was characterized by the parallel stacking of nitro groups, differ in the features of the electron density and electrostatic potential distribution between O and N atoms. The applied electronic criterion, obtained with the use of quantum chemical calculations with periodic boundary conditions, confirmed that for the considered O...N interactions the necessary condition for their classification as pnictogen bonds was met.

Features of the Pnictogen Bonds Formed by Neighboring Nitro Groups in Crystals