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Triphenylbismuth dicrotonate Ph3Bi(O2CCH=CHCH3)2 in benzene solution in the presence of 2-methyl-2-nitrosopropane decomposes in light. The phenyl radicals formed as the result of Ph3Bi(O2CCH=CHCH3)2 decomposition are confirmed by the spin-trapping method; they can initiate the methylmethacrylate polymerization at room temperature. In the absence of light the decomposition has not been observed. Кeywords: electron paramagnetic resonance, triphenylbismuth dicrotonate, 2-methyl-2nitrosopropane.

Decomposition of triphenylbismuth dicrotonate in light in the presence of 2-methyl-2-nitrosopropane