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Investigations on benzimidazole derivatives and their transition metal complexes are of considerable interest owing to their analytical, biological and biochemical significance [1-4]. The coordination of benzimidazole derivatives to metal ions depend on various factors like solvent, stoichiometry, temperature and pH of the media [5-7]. Such factors play significant roles on the composition and geometry of the resulting complexes. In this communication, we report the results of the reactions of iron, cobalt and copper halides with 2-salicylidene4-aminophenyl benzimidazole (SAPbzlH; LH I; LH = (N-NOH). Which would function as monodentate or bridging ligand.

Reactions of Fe(III), Co(II) and Cu(II) Ions with 2-Salicylidene-4-aminophenyl Benzimidazole