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Dithiocarbamate (DTC), a four-electron donating ligand that is capable of either π-electron donation or withdrawal, has played a role in the study of a wide variety of compounds. This monoanionic ligand has been used in the synthesis of lower and higher oxidation state transition metal compounds [1]. The ability of the ligand to adopt dithiocarbamate and thioureide tautomers gives it unique properties to stabilize both lowand high-valent metal ions (Fig.1). The dithiocarbamate form (A) is considered as a soft ligand that is capable in binding to low-valent metal atoms such as tin, while extra negative charge localized on sulfur in the thioureide tautomer (D) is best described as a hard ligand and best suited to high-valent metal binding [2]. The coordination geometry of tin atom in the complexes may be tetrahedral, trigonal-bipyramidal, square-pyramidal, octahedral or pentagonal bipyramidal, depending on the number of organic groups, the coordination mode of CS2 moiety and Spectral Characterization and X-Ray Crystallographic Studies of Some Triphenyltin(IV) Dithiocarbamates Compounds