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STUDY ON THE LEACHING BEHAVIOUR OF LEAD FROM GALENA ORE OF NANGGUNG BOGOR DISTRICT AREA IN ACETIC ACID SOLUTION USING HYDROGEN PEROXIDE AS OXIDIZING AGENT. In the present paper, the results of lead leaching from galena ore received from Nanggung Bogor Regency in acetic acid solution with the presence of hydrogen peroxide as oxidizing agent are presented. Series of bath agitation leaching tests at atmospheric pressure have been carried out to investigate the influences of acetic acid and hydrogen peroxide concentrations, leaching temperature and stirring speed on the extraction percentage of lead. Leaching kinetics was studied at temperatures of 30, 40 and 50 °C by using shrinking core model to determine rate constant, rate determining step and activation energy for lead leaching. The investigation results have demonstrated that lead extraction from galena ore can be well performed by direct leaching of the ore in acetic acid solution in the presence of hydrogen peroxide as oxidizing agent at atmospheric pressure. The highest lead extraction level of 92.3% was obtained from the leaching test with acetic acid and hydrogen peroxide concentrations of 3 and 0.5 molar, respectively, leaching temperature of 50 °C, stirring speed 200 rpm, ore particle size distribution -200 mesh after 90 minute. The hydrogen peroxide concentration must be maintained at certain level in order to avoid the precipitation of lead sulfate that resulted in the decrease of lead extraction percentage. The result of kinetics study revealed that the leaching rate of lead from West Java galena ore in acetit acid and H2O2 solution is controlled by interface reaction with activation energy of 54.52 kJ/mole.

STUDI PERILAKU PELINDIAN TIMBAL DARI BIJIH GALENA NANGGUNG KABUPATEN BOGOR DALAM LARUTAN ASAM ASETAT DAN OKSIDATOR HIDROGEN PEROKSIDA