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Performed phytochemical study contributes to the knowledge of volatile organic compounds (VOCs) of  Halopteris filicina  (Grateloup) Kützing,  Dictyota dichotoma  (Hudson) J. V. Lamouroux,  Posidonia oceanica  (L.) Delile and  Flabellia petiolata  (Turra) Nizamuddin from the Adriatic Sea (single point collection). VOCs were investigated by headspace solid-phase microextraction (HS-SPME) and analysed by gas chromatography and mass spectrometry (GC-MS/FID).  H .  filicina  headspace contained dimethyl sulfide (DMS; 12.8%), C 8 -compounds (e.g. fucoserratene ( I ; 9.5%)), benzaldehyde ( II ; 8.7%), alkane C 17 , dictyopterene D and C ( III ,  IV ), tribromomethane ( V ), 1-iodopentane, others.  F .  petiolata  headspace was characterized by DMS (22.2%), 6-methylhept-5-en-2-one (9.5%), C 17  (9.1%),  II  (6.5%), compounds  I - V . DMS (59.3%), C 15  (14.5%), C 17  (7.2%) and C 19  (6.3%) dominated in  P .  oceanica  headspace. Sesquiterpenes were found in  D .  dichotoma , predominantly germacrene D (28.3%) followed by other cadinenyl (abundant), muurolenyl and amorphenyl structures. Determined VOCs may be significant for chemosystematics and chemical communications in marine ecosystem.

Phytochemical study of the headspace volatile organic compounds of fresh algae and seagrass from the Adriatic Sea (single point collection)