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A synthetic study in the Cd-Se-O-Cl system led to formation of the new oxochloride compound Cd 4 (SeO 3 ) 2 OCl 2  via solid state reactions. The compound crystallizes in the orthorhombic space group  Fmmm  with cell parameters  a  = 7.3610(3) Å,  b  = 15.4936(2) Å,  c  = 17.5603(3) Å, Z = 8, S = 0.969, F(000) = 2800, R = 0.0185, R w  = 0.0384. Single crystal X-ray data were collected at 293 K. The crystal structure can be considered as layered and the building units are distorted [Cd(1)O 6 ] octahedra, distorted [Cd(2)O 8 ] cubes, irregular [Cd(3)O 4 Cl 2 ] polyhedra and SeO 3 E trigonal pyramids. There are two crystallographically unique Cl atoms that both are half occupied. Thermogravimetric studies show that the compound starts to decompose at 500°C. The crystal structure of the new compound is closely related to the previously described compound Cd 4 (SeO 3 ) 2 Cl 4 (H 2 O).

Synthesis, Crystal Structure and Thermal Decomposition of the New Cadmium Selenite Chloride, Cd4(SeO3)2OCl2