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UV laser irradiation (lambda = 193 nm), below and above damage thresholds, isused to both alter and pattern the surface properties of borosilicate slides totune and control the contact angle of a water drop over the surface. Largevariation exceeding 25 deg using laser processing alone, spanning across bothsides of the original contact angle of the surface, is reported. An asymmetriccontact angle distribution, giving rise to an analogous ellipsoidal-like dropcaplet, is shown to improve convective self-assembly of silica nanoparticlesinto straighter microwires over a spherical caplet.

Tailoring surface interactions, contact angles, drop topologies and self-assembly using laser irradiation