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Efficiency of thermoradiative cells can be increased by selecting high-entropy infrared photons for radiative energy exchange. Near-field coupling to phonon polaritons in the heat sink further increases both conversion efficiency and power density.United States. Dept. of Energy. Division of Materials Sciences and Engineering (Award DE-FG02-02ER45977)United States. Department of Energy. Office of Basic Energy Sciences (Solid-State Solar-Thermal Energy Conversion Center. Award DE-SC0001299/DE-FG02-09ER46577

Photon Entropy Control and Near-Field Radiative Coupling Improve Efficiency of Thermoradiative Cells