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Fast time-resolved infrared (TRIR) spectroscopy has been used to study a wide range of organometallic alkane and noble-gas complexes at ambient temperature. We have shown that the reactivity of the n-heptane complexes decreases both across and down Groups V, VI, and VII, and that the corresponding xenon complexes have similar reactivities.

Organometallic alkane and noble-gas complexes in conventional and supercritical fluids