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The capabilities of porcine pancreatic lipase (PPL),  Candida antarctica  lipase (CAL), and  Candida rugosa  lipase (CRL) were evaluated for enantio- and/or regioselective acetylation/deacetylation of (±)-2,4-diacetoxyphenyl alkyl ketones, (±)-4-alkyl-3,4-dihydro-3-hydroxyalkyl-2 H -1,3-benzoxazines, and d- arabino  and d- threo -polyhydroxyalkyltriazoles in organic solvents. PPL in tetrahydrofuran (THF) exhibited high to moderate enantioselectivity during the deacetylation of (±)-2,4-diacetoxyaryl alkyl ketones and acetylation of (±)-3-hydroxyalkyl-2 H -1,3-benzoxazines. Together with enantioselectivity, PPL in THF also showed exclusive regioselectivity for the deacetylation of  para -acetoxy over the  ortho -acetoxy function, with respect to the nuclear carbonyl group in 2,4-diacetoxyphenyl alkyl ketones. CAL in diisopropyl ether (DIPE) and PPL in THF exhibited exclusive selectivity for the acetylation of primary hydroxyl over secondary hydroxyl group(s) of d- arabino - and d- threo -polyhydroxyalkyltriazoles.

Selective biotransformation reactions on (±)-aryl alkyl ketones, (±)-benzoxazines, and d-arabino- and d-threo-hydroxyalkyltriazoles