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Camphor-derived oxazoline-N-oxides are versatile dipoles in a new kind of asymmetric [2+3] cycloadditions. Recent applications of this methodology allowed the stereoselective syntheses of several b-lactones natural products such as 1233A and tetrahydrolipstatine. Two formal syntheses of b-lactams antibiotics, b-methyl thienamycin and carpetimycin A, have also been achieved using this type of cycloaddition.

Oxazoline-N-oxide mediated asymmetric cycloadditions. Recent progress in the stereo-selective syntheses of β-lactones and β-lactams