English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The Gif systems permit the selective finctionalization of saturated hydrocarbons under mild conditions and with high efficiencies. A newly discovered Fen-Fe" manifold is shown to form alkyl chlorides by a process involving carbon- centered radicals as intermediates. This is distinct from the usual ketonization process (Gif Chemistry) produced by an Fern-Fe" manifold. The importance of certain carboxylic acids such as picolinic acid for hydrocarbon activation has been demonstrated. The ligand environment of the catalyst in solution is clarified using quantitative 13C-NMR spectroscopy. Evidence for a p-peroxo dimer species as a key intermediate in solution is provided and recent mechanistic studies are reported.

The selective functionalization of saturated hydrocarbons: Recent developments in Gif chemistry