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The contribution of N.N. Semenov to the chemistry of the 20th century is described including his discovery of branching chain reactions and the development of the general theory of chain reactions and thermal explosions. Particular emphasis is made on his early understanding of the necessery to introduce modem physical concepts into new chemistry as well as his prediction that biology is likely to play a crucial role in the future chemistry.

N. N. Semnov and the chemistry of 20th century (to 100th anniversary of his birth)