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Calorimetric measurements of the differential molar adsorption h eat of nonpolar m olecules onto molecu- lar sieves reveal that the initial adsorption heats - increase linearly with the molar aluminium fraction of the adsorbents, which have the same crystal structure but different chemical composition and also - increase with the framework density of the adsorbents, which have the same chemical c omposition but different crystal struoture.

pure and applied chemistry

Correlation between initial heats of adsorption and structural parameters of molecular sieves with different chemical composition - a calorimetric study