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In the context of the theory of materials design, we consider the role of adsorption — at free surfaces and intercrystalline interfaces — on kinetic phenomena which in turn influence significantly the mechanical and processing properties of materials. In particular, we discuss gas phase surface hardening reactions, grain boundary mass transport and precipitate ripening processes, with a view to establishing guidelines for improved performance, through an understanding of the nature and effects of adsorbing species.

Interfacial adsorption and reactivity of materials