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Heat and mass transfer phenomena may induce structural changes in polymeric materials; the kinetics of such changes are then coupled with those of the transport processes. Two categories of phenomena are considered: bulk structural changes taking place gradually throughout the polymers, and abrupt changes taking place at a surface of morphological discontinuity. For both categories both the physics and the mathematics are discussed in some detail. The content of this paper is largely a review of recent results, though some of the points presented are original ones.

Physics and mathematics of heat and mass transfer in polymers