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In the following work the current status of inorganic phosphate chemistry is discussed briefly. The influence of phase transitions upon the physical properties of condensed phosphates is reviewed and new data for the 54°C transition of Na 4 P 4 O 12 ·4H 2 O are presented. Urea will prevent the decomposition of Na 5 P 3 O 10 during the transition of Na 5 P 3 O 10 ·6H 2 O to Na 5 P 3 O 10 . The mechanism of this action is discussed. The growths of cleavage families resulting from the hydrolytic degradation of condensed phosphates are discussed, and published rate constants are employed to calculate the growth of families of phosphates.

The chemical and physical properties of condensed phosphates