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Coordination compounds, organo-transition metal clusters, metalloproteins and metal surfaces provide many and varied examples of polynuclear complexes. The structural data of such simple examples as dimethylberyllium, triphenyl-aluminium and their electron-precise counterparts—beryllium dichloride and the aluminium trihalides—can be rationalized through a recognition of the symmetry and occupancy of the bridge molecular orbitals. A simple model of the bonding in binuclear transition metal complexes is summarized. In the case of the redox centres of the metal–sulphur proteins, useful predictions are available from the data on ‘model’ complexes. The potential of cluster complexes to stabilize reactive organic species such as benzyne is touched upon by way of an introduction to a brief survey of some recent developments in surface organometallic chemistry.

Structural inorganic chemistry and diffraction methods: metal-ligand bonds in polynuclear complexes and on metal surfaces