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Rotating-bomb calorimetry was first applied to organic compounds that contain chlorine, bromine, or sulphur. Techniques developed for these classes of compounds, mostly at the University of Lund and at the Bureau of Mines in Bartlesville, have been described in the book Experimental Thermochemistry-, The development of rotating-bomb methods made accurate combustion calorimetry feasible for other classes of compounds besides those of chlorine, bromine, or sulphur. Two of these other classes of compounds have received attention in the Bureau of Mines laboratory in recent years, namely: (a) organic fluorine compounds and (b) organometallic compounds and other carbon compounds of metals. Techniques developed for rotating-bomb calorimetry of these two classes of compounds are reviewed in this paper.

Thermochemistry of organic fluorine compounds and carbon compounds of metals by rotating-bomb calorimetry