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Recent advances in radical azidation using sulfonyl azides are presented. For instance, radical carboazidation using α - iodoketones, desulfitative carboazidation, and  anti -Markovnikov hydroazidation of alkenes are described. These novel methods tolerate a large number of functional groups and allow the synthesis of organic azides that would be difficult to synthesize otherwise. The transformation of the azides using reductive processes as well as a Schmidt reaction under nonacidic conditions were used to synthesize alkaloids including indolizidine 167B, monomorine I, cylindricine C, and lepadiformine C.

Radical azidation reactions and their application in the synthesis of alkaloids