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We report recent progress on Au- and Pt-catalyzed cascade reactions to access complicated molecular frameworks. Reported reactions include new cyclization/cycloaddition cascades on carbonyl and epoxide substrates tethered with an allene, alkene, and alkyne. Such substrates enable Au-catalyzed cascade reactions comprising an initial cyclization to form reactive 1, n -dipole that undergoes subsequent cycloadditions with suitable dipolarophiles.

Access to molecular complexity via gold- and platinum-catalyzed cascade reactions