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A new Schiff base ligand (L1) was prepared from 3-aminoquinoline with 2,5 dimethoxybenzaldehyde in 1:1 molar ratio. Two different co-ordination of mononuclear metal(II) complexes [(ML1) & (ML1L2)] [ M = Co(II), Ni(II), Cu(II) and Zn(II)] were synthesized & characterized. ML1 were prepared from L1 and metal acetate salts molar proportion One:Two. ML1L2 synthesized from L1, metal salts and 8-hydroxy quinoline (L2) molar ratio is 1:1:1. Elemental analyses, IR, NMR, Electronic spectra, Mass spectra, EPR, SEM and Powder XRD & molar conductivity are need to clarify the structure of synthesized metal(II) complexes. The square planar geometry is proposed for CuL1, NiL1, ZnL1, NiL1L2 and ZnL1L2, tetrahedral geometry for CoL1 & CoL1L2 and distorted square planar geometry for CuL1L2 complex. Powder XRD reveals that L1, ML1 & ML1L2 have crystalline nature. Antibacterial activity of Ligand, ML1 & ML1L2 were screened against bacterium Gram(+), Gram(-) & antifungal activity was determined against fungus. The anti-inflammatory and anti-diabetic actions of the L1, CuL1 & CuL1L2 complexes were studied. The anticancer activity of L1, CuL1 and CuL1L2 were studied opposed to MCF-7 using MTT assay method.

oriental journal of chemistry/oriental journal of chemistry

Synthesis,Characterization, biocidal, Anti-diabetic, Anti-inflammatory and Anti-Cancer(MCF-7) Studies of Schiff base ligand and its metal (II) complexes