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MoOCl4 reacts with 1-methylimidazole, 4-methylpiperidine and trimethylsilylimidazole (equimolar molar amounts) in solvent CH3CN to provide MoO2Cl4(C3H3N2CH3) [1], MoOCl4(C5H9NHCH3)CH3CN [4] and MoO2Cl2(C3H4N2), [7]. MoOCl4 reacts with twice the moles of 1,4-diaminobutane, 2-methylpyridine, 4-methylpiperidine and 1-methylpyrrolidine in solvent CH3CN to provide: MoOCl4(H2NC4H8NH2)2 [2], MoOCl4(C5H4NCH3), [3], MoOCl4(C5H9NHCH3)2, [5], MoOCl4(C5H9NHCH3)2, [6] and MoO2Cl4(C4H8NCH3)2, [8]. Complexes have been studied by techniques: elemental quantitative analysis, FTIR, 1H NMR, Mass (LC-MS).

Reactions of MoOCl4 with 1-Methylimidazole, 1,4-Diaminobutane, 2-Methylpyridine, 2-Methylpiperidine, Trimethylsilylimidazole and 1-Methylpyrrolidine